Remove duplicate constraints in requirements/constraints.txt uncovered by the recent change in pip-compile output format. I sorted the pinned dependencies by name to try and make it more obvious if this happens again. I also upgraded to pip-tools 4.5.1, which removes the line numbers from the enhanced pip-compile output added in 4.5.0, which should reduce future diff churn and merge conflicts but means that there's a large diff this one last time.

Also unpin edx-search again after the previous change to do that was apparently broken by a merge conflict.